Synthesis and characterization of metal complexes of a novel Schiff base
ABSTRACT:
The Fe(III), Ru(III), Co(II), Ni(II), Cu(II), Pd(II), Zn(II), Cd(II) and Hg(II) complexes of a Schiff base derived from pyrazine-2-carboxamide and thiophene-2-carbaldehyde (PZATA: 1) have been synthesized and structurally characterized by various physico-chemical data. The ligand acts as a neutral, bidentate one towards the metal ions coordinating through azomethine nitrogen and thiophene sulphur. The geometry and the bonding characteristics associated with the complexes have been deduced from relevant spectral data. Further ,the ligand and the metal complexes have been screened for their antimicrobial activity and the results are presented.
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The Fe(III), Ru(III), Co(II), Ni(II), Cu(II), Pd(II), Zn(II), Cd(II) and Hg(II) complexes of a Schiff base derived from pyrazine-2-carboxamide and thiophene-2-carbaldehyde (PZATA: 1) have been synthesized and structurally characterized by various physico-chemical data. The ligand acts as a neutral, bidentate one towards the metal ions coordinating through azomethine nitrogen and thiophene sulphur. The geometry and the bonding characteristics associated with the complexes have been deduced from relevant spectral data. Further ,the ligand and the metal complexes have been screened for their antimicrobial activity and the results are presented.
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