Study on removal of hexavalent chromium [VI] from aqueous solution using beach sand
ABSTRACT:
The use of fine beach sand to remove hazardous Chromium [VI]
ions from aqueous solutions was investigated. Removal of chromium ions from
stock solution of known concentration of Potassium dichromate was carried out
by two sand samples, one pretreated with 70% nitric acid and one washed with
distilled water. The experiment was carried out as a function of pH, where the
nitric acid pretreated sand had a pH=1, and the water-pretreated sand had a
pH=7. The experiment was carried out at room temperature (31°C). The adsorption
time for both the solutions was 180 minutes. The main principle of this
experiment was the adsorption of chromium [VI] ions to the sand particles. The
rate of removal of chromium [VI] ions was observed both qualitatively as well
as quantitatively. Higher removal of chromium ions was obtained at pH=1
compared to pH=7 sand samples. For Cr [VI], the Langmuir isotherm gave the best
fit for adsorption. The results are discussed in terms of the chromium species
present in the solution and the effect of contact time and pH on the rate of
adsorption and removal efficiency has been studied.
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